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Ultraviolet rays with a UV-C wavelength will destroy pathogens such as viruses, bacteria, mold, and mildew. This component of sunlight is the main reason that microorganisms die in outdoor air. The UV-C rays break through the outer membrane of microbes like yeast, mold, bacteria, viruses, or algae. When the radiation reaches the DNA of the microbe, it causes modifications. The DNA then transmits incorrect codes and this causes the death of the microbe.

Ultraviolet germicidal lamps provide a much more powerful and concentrated effect of ultraviolet energy than can be found naturally. Such lamps sanitize air that is passed directly in their path to destroy pathogens that come in contact with the UV rays. Musty, moldy type odors can be eradicated, along with tuberculosis, cold and flu viruses, smallpox, anthrax, and other airborne diseases. This system is particularly beneficial to those suffering from allergies-common allergens are molds, mildews, and fungi. These microbes would be destroyed, improving the health of the allergy sufferer.

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The Mechanism of Photocatalysis

When photocatalyst titanium dioxide (TiO2) absorbs Ultraviolet (UV)* radiation from sunlight or illuminated light source (fluorescent lamps), it will produce pairs of electrons and holes.
The electron of the valence band of titanium dioxide becomes excited when illuminated by light. The excess energy of this excited electron promoted the electron to the conduction band of titanium dioxide therefore creating the negative-electron (e-) and positive-hole (h+) pair. This stage is referred as the semiconductor's 'photo-excitation' state. The energy difference between the valence band and the conduction band is known as the 'Band Gap'. Wavelength of the light necessary for photo-excitation is:
1240 (Planck's constant, h) / 3.2 ev (band gap energy) = 388 nm

photocatalysis

 

BASIC FUNCTIONS OF PHOTOCATALYSIS

1.Sterilizing Effect

Photocatalyst does not only kill bacteria cells, but also decompose the cell itself. The titanium dioxide photocatalyst has been found to be more effective than any other antibacterial agent, because the photocatalytic reaction works even when there are cells covering the surface and while the bacteria are actively propagating. The end toxin produced at the death of cell is also expected to be decomposed by photocatalytic action. Titanium dioxide does not deteriorate and it shows a long-term anti-bacterial effect. Generally speaking, disinfections by titanium oxide is three times stronger than chlorine, and 1.5 times stronger than ozone.

2. Deodorizing Effect

On the deodorizing application, the hydroxyl radicals accelerate the breakdown of any Volatile Organic Compounds or VOCs by destroying the molecular bonds. This will help combine the organic gases to form a single molecule that is not harmful to humans thus enhance the air cleaning efficiency. Some of the examples of odor molecules are: Tobacco odor, formaldehyde, nitrogen dioxide, urine and fecal odor, gasoline, and many other hydro carbon molecules in the atmosphere. Ti02 can prevent smoke and soil, pollen, bacteria, virus and harmful gas as well as seize the free bacteria in the air by filtering percentage of 99.9% with the help of the highly oxidizing effect of photocatalyst (Ti02).

3. Air Purifying Effect

The photocatalytic reactivity of titanium oxides can be applied for the reduction or elimination of polluted compounds in air such as NOx, cigarette smoke, as well as volatile compounds arising from various construction materials. Also, high photocatalytic reactivity can be applied to protect lamp-houses and walls in tunneling, as well as to prevent white tents from becoming sooty and dark. Atmospheric constituents such as chlorofluorocarbons (CFCs) and CFC substitutes, greenhouse gases, and nitrogenous and sulfurous compounds undergo photochemical reactions either directly or indirectly in the presence of sunlight. In a polluted area, these pollutants can eventually be removed.

 
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